Relative Stability of cis- and trans-Hydrindanones

The relative stabilities of several cis- and trans-hydrindanones were compared using both isomerization experiments and MM2 calculations. The generally believed rule that cis-hydrindanones are more stable than trans-isomers is applicable, but is not always true. This review introduces examples, main...

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Bibliographic Details
Main Author:	Motoo Tori
Format:	Article
Language:	English
Published:	MDPI AG 2015-01-01
Series:	Molecules
Subjects:	hydrindanones isomerization isomer stereochemistry stability MM2
Online Access:	http://www.mdpi.com/1420-3049/20/1/1509

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record_format	Article
spelling	doaj-000a35a8d53d4d888fba71fca7e064842020-11-25T00:00:36ZengMDPI AGMolecules1420-30492015-01-012011509151810.3390/molecules20011509molecules20011509Relative Stability of cis- and trans-HydrindanonesMotoo Tori0Faculty of Pharmaceutical Sciences, Tokushima Bunri University, Yamashiro-cho, Tokushima 770-8514, JapanThe relative stabilities of several cis- and trans-hydrindanones were compared using both isomerization experiments and MM2 calculations. The generally believed rule that cis-hydrindanones are more stable than trans-isomers is applicable, but is not always true. This review introduces examples, mainly from studies in our laboratory, to explain these facts.http://www.mdpi.com/1420-3049/20/1/1509hydrindanonesisomerizationisomerstereochemistrystabilityMM2
collection	DOAJ
language	English
format	Article
sources	DOAJ
author	Motoo Tori
spellingShingle	Motoo Tori Relative Stability of cis- and trans-Hydrindanones Molecules hydrindanones isomerization isomer stereochemistry stability MM2
author_facet	Motoo Tori
author_sort	Motoo Tori
title	Relative Stability of cis- and trans-Hydrindanones
title_short	Relative Stability of cis- and trans-Hydrindanones
title_full	Relative Stability of cis- and trans-Hydrindanones
title_fullStr	Relative Stability of cis- and trans-Hydrindanones
title_full_unstemmed	Relative Stability of cis- and trans-Hydrindanones
title_sort	relative stability of cis- and trans-hydrindanones
publisher	MDPI AG
series	Molecules
issn	1420-3049
publishDate	2015-01-01
description	The relative stabilities of several cis- and trans-hydrindanones were compared using both isomerization experiments and MM2 calculations. The generally believed rule that cis-hydrindanones are more stable than trans-isomers is applicable, but is not always true. This review introduces examples, mainly from studies in our laboratory, to explain these facts.
topic	hydrindanones isomerization isomer stereochemistry stability MM2
url	http://www.mdpi.com/1420-3049/20/1/1509
work_keys_str_mv	AT motootori relativestabilityofcisandtranshydrindanones
_version_	1725444354644901888

Relative Stability of cis- and trans-Hydrindanones

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