Carbon Ligands From Fundamental Aspects to Applications

• Format: eBook
• Language: English
• Published: Basel, Switzerland MDPI - Multidisciplinary Digital Publishing Institute 2021
• Subjects: Research and information: general; 195Pt NMR; alkali metals; amide; amino-acids; aromaticity; asymmetric synthesis; calixarene; carbenes; carbido complexes; carbodiphosphorane; carbon ligand; carbone; carbone complexes; catalysis; chemical bonding; chirality; coordination; coordination chemistry; copolymerization of epoxide with CO2; Cu(I) complex; cyclooctatetraene ions; dehydrogenation; density functional theory; density functional theory (DFT); DFT calculations; drug resistance; electrochemistry; electron paramagnetic resonance (EPR) spectroscopy; electronic structure; germylene; gold; hafnium; hybrid molecules; imidazole; intramolecular C-H activation; ion pairs; ligand; ligands; lithium; macrocycle; malaria; mercury(II) complex; metal complexes; metathesis; N-heterocyclic carbene; N-heterocyclic carbenes; n/a; nanoparticle; natural bond orbitals; negative charge; NHC; NHC ligands; NHC-ligands; nitro catalysts; olefins; optical resolution; oxide; palladium catalyst; phosphonium ylide; phosphorus ylides; photoluminescence; pincer; pincer ligand; pincer ligands; Plasmodium falciparum; platinum; potassium; reactivity; rhodium; ruthenium; selenonium salts; selenonium ylides; spectroscopy; stereogenic selenium atom; structure-activity relationship; Suzuki-Miyaura reaction; T-shaped; titanium; transition metal complexes; tropylidenyl ions; water; X-ray; ylide; ylides
• Online Access: Open Access: DOAB: description of the publication; Open Access: DOAB, download the publication

 Homogeneous catalysis owes its success, in large part, to the development of a wide range of ligands with well-defined electronic and steric properties, which have thus made it possible to adjust the behavior of many organometallic complexes. However, ligands used in catalysis have long been centered on elements of group 15, and it is only more recently that carbon ligands have proved to be valuable alternatives with the emergence of cyclic diaminocarbenes (NHC).This Special Issue aims to provide a contemporary overview of the advances in carbon ligand chemistry from fundamental aspects to applications.